Show simple item record

dc.contributor.authorLimo, Samuel K
dc.date.accessioned2013-05-23T15:12:05Z
dc.date.available2013-05-23T15:12:05Z
dc.date.issued1998
dc.identifier.citationMScen
dc.identifier.urihttp://erepository.uonbi.ac.ke:8080/xmlui/handle/123456789/25026
dc.descriptionDegree of Master of Scienceen
dc.description.abstractA survey of the literature revealed that most palm oil imports carried the exporter's specifications which created undue disputes that took long periods to settle while the oil remained stored under varying conditions at the point of destination; that such imports were likely to be affected by certain conditions of storage, transportation and handling; and that no comprehensive studies had been carried out to establish critical parameters that could be used to characterise these imports and hence provide a correct assessment of their market value and appropriate tax, valuation in Kenya. Palm oil samples from eight ex-Malaysia and Indonesia shipments were collected from twenty-three storage tanks at Mombasa port over a period of ten months. The objective was to investigate the characteristics of the oil in relation to possible effects of handling, storage and transportation. Mean density and refractive index when determined at 50 ± O.l°C were found to be 0.8905 g/ml and 1.4548, respectively. The iodine value and softening point'were found to be 52.2 and 36.8°C, respectively; whIle saponification value and unsaponifiable matter content fluctuated around 197 mgKOH/g and 0.43%, respectively. Further investigations with unsaturated fatty acids using the Wij's iodine addition method revealed that the iodine value (Y) for varying amounts of palm oil (X) can be corrected using the equation: Y = -0.6203X + 52.666, thus enabling an optimum standardization of the weight range (0.31 < X < 1.21 g) of the oil for testing. The content of carotenoids (expressed as beta-carotene) was found to be 496 + 21 ppm; while the free fatty acid content (as palmitic acid equivalent and volatile matter were 3.47% and 0.12%, respectively. The values of density, softening point, saponification value and refractive index were generally higher t~an those reported from palm oil surveys in Malaysia; while refractive index, iodine value. - free fatty acid content. unsaponifiable mat.t.er-,' carotenoids content and volatile matter were lower. A study of the variation of viscosity of palm oil. measured at temperatures between 25 and 90°C yielded data which gave two regression lines that intersected at 48.1°C, a valhe taken as the critical temperature for.viscous flow of-palm oil. These results can be used as reference properties for -the grading of palm oil imports as well as correct tax'valuation; and for categorizing those imports that may require further processing in this country. Strategies and priorities have also been proposed for further investigations concentrating on the iodine value, carotenoids content and the viscosity-temperature relationship, as critical parameters that can be used to assess palm oil imports. In this way constraints on revenue collection by the relevant tax agencies will be identified and alleviated.en
dc.language.isoenen
dc.titlePhysico-chemical properties and characteristics of palm oilen
dc.typeThesisen
local.publisherSchool of Biological Sciences, University of Nairobien


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record