Studies of dioxamide and dithio-oxamide metal complexes. Part 2. Synthesis and spectral characterisation of RNHC(S)C(S)NHR (R = alkyl or aryl) complexes with SbX3(X = Cl or Br), BiCl3, SnX4(X = Cl or Br), and TiCl4. Crystal and molecular structures of NN′-di-isopropyldithio-oxamide (L3) and SbCl3(L3)1.5
Date
1984Author
Drew, Michael GB
Kisenyi, Jonathan M
Willey, Gerald R
Wandiga, Shem O
Type
ArticleLanguage
enMetadata
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The synthesis and characterisation of a variety of SbX3L1.5(X = Cl or Br), BiCl3L2, SnX4L (X = Cl or Br), and TiCl4L complexes [where L = RNHC(S)C(S)NHR for R = Me, Et, Pri, Bun, cyclo-C6H11, or CH2Ph] is described. In all cases metal–sulphur bonds are formed following SS′-bidentate ligand attachment. The potential N-donor sites are not involved in co-ordination. The structural characterisation of the uncomplexed ligand PriNHC(S)C(S)NHPri(L3) and the antimony(III) complex SbCl3(L3)1.5(1) are reported. Crystals of (1) are rhombohedral, space group R[3 with combining macron] with a= 11.80(1)Å, α= 60.1 (1)°, and Z= 2. 1 089 Unique data above background were collected and the structure refined to R 0.068. Crystals of L3 are monoclinic, space group P21/c with a= 6.226(7), b= 8.067(11), c= 11.187(12)Å, β= 91.0(1)°, and Z= 2. 635 Data above background were measured and the structure refined to R 0.077. The structure of (1) is a three-dimensional polymer. The octahedrally co-ordinated Sb atom lies on a three-fold axis and is strongly bound to three chlorine atoms [2.413(2)Å] and also weakly bound to three sulphur atoms from different ligands, which approach their positions trans to chlorine [Sb–S 3.197(5)Å] thus giving rise to an octahedral environment. There is no evidence for a stereochemically active lone pair associated with SbIII. In the structure of L3 the sulphur atoms are mutually trans[C–S 1.680(7)Å] and this orientation is retained on complexation.
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http://pubs.rsc.org/en/content/articlelanding/1984/dt/dt9840001717http://erepository.uonbi.ac.ke:8080/xmlui/handle/123456789/34096
Citation
J. Chem. Soc., Dalton Trans., 1984, 1717-1721; DOI: 10.1039/DT9840001717Publisher
University of Nairobi College of Biological and Physical Sciences