dc.contributor.author | Angeyoa, KH | |
dc.contributor.author | Garib, S | |
dc.contributor.author | Mustapha, AO | |
dc.contributor.author | Mangala, JM | |
dc.date.accessioned | 2013-06-30T12:30:28Z | |
dc.date.available | 2013-06-30T12:30:28Z | |
dc.date.issued | 2012-11 | |
dc.identifier.citation | Applied Radiation and Isotopes Volume 70, Issue 11, November 2012, Pages 2596–2601 | en |
dc.identifier.uri | http://www.sciencedirect.com/science/article/pii/S0969804312004526 | |
dc.identifier.uri | http://erepository.uonbi.ac.ke:8080/xmlui/handle/123456789/42963 | |
dc.description.abstract | The greatest challenge to material characterization by XRF technique is encountered in direct trace analysis of complex matrices. We exploited partial least squares (PLS) in conjunction with energy dispersive X-ray fluorescence and scattering (EDXRFS) spectrometry to rapidly (200 s) analyze lubricating oils. The PLS–EDXRFS method affords non-invasive quality assurance (QA) analysis of complex matrix liquids as it gave optimistic results for both heavy- and low-Z metal additives. Scatter peaks may further be used for QA characterization via the light elements. | en |
dc.language.iso | en | en |
dc.publisher | University of Nairobi | en |
dc.subject | X-ray fluorescence scattering complex matrix liquids; Chemometrics; Modeling | en |
dc.title | Feasibility for direct rapid energy dispersive X-ray fluorescence (EDXRF) and scattering analysis of complex matrix liquids by partial least squares | en |
dc.type | Article | en |
local.publisher | Institute of Nuclear Science and Technology | en |