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Observations on the Low-Energy Limits for Metal-to-Ligand Charge-Transfer Excited-State Energies of Ruthenium(II) Polypyridyl Complexes
(2010)
The 77 K emission spectral maxima of bis(bipyridine)ruthenium(II) complexes are found to approach a limit at energies below about 14 000 cm−1. There is also evidence for related low-energy excited-state limits in some other ...
Effects of Electronic Mixing in Ruthenium(II) Complexes with Two Equivalent Acceptor Ligands. Spectroscopic, Electrochemical, and Computational Studies
(2010)
The lowest energy metal to ligand charge transfer (MLCT) absorption bands found in ambient solutions of [Ru(NH3)4(Y-py)2]2+ and [Ru(L)2(bpy)2]+ complexes (Y-py a pyridine ligand and (L)n a substituted acetonylacetonate, ...