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    Observation of Meyer-Neldel rule in Se 100− XM (M= In, Sb) X chalcogenide glasses

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    Date
    2015
    Author
    Maabong, Kelebogile
    Mwabora, Julius M
    Sathiaraj, T S
    Muiva, Cosmas M
    Type
    Article; en
    Language
    en
    Metadata
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    Abstract
    Non-isothermal Differential Scanning Calorimetric (DSC) studies were done on Se100−XM(M=In, Sb)X chalcogenide glasses prepared by the melt quenching technique. The composition-dependent activation energy for glass to crystal transformation (ΔEc) and the pre-exponential factor (Ko) of the Arrhenius expression were obtained on the basis of the Augis and Bennett׳s method. A linear dependence between ΔEc and lnK0 was observed in both systems implying the existence of compensation effects of the Meyer-Neldel type. These compensation effects confirmed the applicability of Meyer-Neldel Rule (MNR) for the non-isothermal crystallization in the present systems.
    URI
    http://www.sciencedirect.com/science/article/pii/S0272884214015703
    http://hdl.handle.net/11295/81688
    Citation
    Muiva, Cosmas M., T. S. Sathiaraj, Julius M. Mwabora, and Kelebogile Maabong. "Observation of Meyer-Neldel rule in Se 100− X M (M= In, Sb) X chalcogenide glasses." Ceramics International 41, no. 2 (2015): 2348-2352.
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