Show simple item record

dc.contributor.authorSila, Andrew
dc.contributor.authorShepherd, Keith
dc.contributor.authorPokhariyal, Ganesh
dc.contributor.authorTowett, Erick T
dc.contributor.authorWeullow, Elvis
dc.contributor.authorMercy, Nyambura
dc.date.accessioned2015-06-19T14:55:33Z
dc.date.available2015-06-19T14:55:33Z
dc.date.issued2015
dc.identifier.citationGeophysical Research Abstracts vol. 17,EGU2015-PREYIEW, 2015en_US
dc.identifier.urihttp://hdl.handle.net/11295/85230
dc.description.abstractWe propose a method for improving soil property predictions using local calibration models trained on datasets in spectral subspaces rather that in a global space. Previous studies have shown that local calibrations based on a subset of spectra based on spectral similarity can improve model prediction performance where there is large population variance. Searching for relevant subspaces within a spectral collection to construct local models could result in models with high power and small prediction errors, but optimal methods for selection of local s~les are not clear. Using a self-organizing map method (SOM) we obtained four mid-infrared subspaces for 1,907 soil sample spectra collected from 19 different countries by the Africa Soil Information Service. Subspace means for four sub-spaces and five selected soil properties were: pH, 6.0, 6.1, 6.0, 5.6; Mehlich-3 AI, 358, 974, 614, 1032 (mg/kg); Mehlich-B Ca, 363, 1161,526,4276 (mg/kg); Total Carbon, OA, 1.1,0.6,2.3 (% by weight), and Clay (%), 16.8, 46A, 27.7, 63.3. Spectral subspaces were also obtained using a cosine similarity method to calcelate the angle between the entire sample spectra space and spectra of 10 pure soil minerals. We found the sample soil spectra to be similar to four pure minerals distributed as: Halloysite (nl=214), illite (n2=743), Montmorilleaite (n3=914) and Quartz (n4=32). Cross-validated partial least square regression models were developed using two-thirds of samples spectra from each subspace for the five soil properties. We evaluated prediction performance of the models using the root mean square error of prediction (RMSEP) for a one-third-holdout set. Local models significantly improved prediction performance compared with the global model. The SOM method reduced RMESP for total carbon by 10 % (global RMSEP = OAl) Mehlich-3 Ca by 17% (global RMESP = 1880), Mehlich-3 Al by 21 % (global RMSEP = 206), and clay content by 6 % (global RMSEP = 13.6), but not for pH. Individual SOM groups gave up to 94% reduction in RMSEP for total carbon, compared with the global model. Overall SOM gave better predictions than the cosine method but the latter is worth researching further as it may provide additional interpretative insight into soil mineralogical differences.en_US
dc.language.isoenen_US
dc.titleUsing spectral subspaces to improve infrared spectroscopy prediction of soil propertiesen_US
dc.typeArticleen_US
dc.type.materialenen_US


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record